Synthesis of a cumyl analogue in nitrothiazole series and S(RN)1 reaction at tertiary carbon

DOI: 10.1016/S0040-4039(97)00243-8

Source and publish data:

Tetrahedron Letters p. 2085 - 2086 (1997)

Update date:2022-08-17

Topics:

Authors:

Gellis, Armand

Vanelle, Patrice

Maldonado, Jose

Crozet, Michel P.

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Article abstract of DOI:10.1016/S0040-4039(97)00243-8

A new alkylating agent, 2-(1-methyl-1-nitroethyl)-5-nitrothiazole, bearing a tertiary nitro nucleofuge, reacts with 2-nitropropane anion by S(RN)1 mechanism leading to the C-alkylation product.

Full text of DOI:10.1016/S0040-4039(97)00243-8

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