The enantioselective chalcogeno-Baylis-Hillman reaction using a chiral hydroxy chalcogenide-TiCl4 complex

DOI: 10.1246/cl.1999.257

Source and publish data:

Chemistry Letters p. 257 - 258 (1999)

Update date:2022-08-17

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Authors:

Kataoka, Tadashi

Iwama, Tetsuo

Tsujiyama, Shin-Ichiro

Kanematsu, Kiyoko

Iwamura, Tatsunori

Watanabe, Shin-Ichi

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Article abstract of DOI:10.1246/cl.1999.257

The enantioselective chalcogeno-Baylis-Hillman reaction was investigated by the use of chiral hydroxy chalcogenides in the presence of TiCl₄ under atmospheric pressure. The best result was obtained with 10-methylthioisobornenol as a chiral hydroxy chalcogenide.

Full text of DOI:10.1246/cl.1999.257

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