Unexpected Dehydrogenation of a Cyclohexyl Group at Low Temerature through Protonation of RuH3(η5-C5Me5)(PCy3) (Cy = cyclohexyl). X Ray Structure of 5-C5Me5)Ru((C6H9)P(C6H11)2)>BF4

DOI: 10.1039/c39880000998

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 998 - 1000 (1988)

Update date:2022-08-16

Topics:

Authors:

Arliguie, Therese

Chaudret, Bruno

Jalon, Felix

Lahoz, Fernando

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000998

Low temperature protonation of RuH3(η₅-C5Me5)(PR3) (R = Prⁱ, Ph, cyclohexyl) leads either to decomposition (R = Prⁱ) to a mixture of cis- and trans-5-C5Me5)(PR3)2>BF4 (R = Ph), or to dehydrogenation of a cyclohexyl group to afford the complex 5-C5Me5)((C6H9)P(C6H11)2)>BF4 which shows a strong agostic interaction beween a C-H bond of the cyclohexyl group and the metal; a possible application of the later observation is proposed for the dehydrogenation of alkenes.

Full text of DOI:10.1039/c39880000998

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:TRIISOPROPYLPHOSPHONIUM TETRAFLUOROBORATE

Cas No:121099-07-8

R&D Labs maybe for 121099-07-8

Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Anhui Redstar Pharmaceutical Corp., Ltd

Contact:+86-563-5120837

Address:Jingxian Industrial Development Zone, Anhui , China
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
MiHecb Bio-Tech Co., Ltd.

Contact:+86-0592 5353131

Address:No.56 Guani Road Software Park 2,Siming District
ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai

Relevant to this article

Synthesis and biological activities of novel S-β-D-glucopyranoside derivatives of 1,2,4-triazole

Doi:10.1080/10426507.2021.1901704
(2021)
Versatile functionalization of polylysine: Synthesis, characterization, and use of neoglycoconjugates

Doi:10.1021/ja984183p
(1999)
An efficient, selective and inexpensive supported oxidant for the regeneration of carbonyl compounds from oximes, semicarbazones, 4- phenylsemicarbazones, and p-nitrophenyldrazones

Doi:10.1080/00397910008087230
(2000)
Hydrogen bonding-inspired organocatalysts for CO₂ fixation with epoxides to cyclic carbonates

Doi:10.1016/j.cattod.2015.08.062
(2016)
Catalytic application of zeolites in the methanol conversion to hydrocarbons

Doi:10.1246/cl.2002.672
(2002)
Dependence of catalytic activity of metal-containing particles on degree of ordering rather than on size and shape. Pd and Ni-catalyzed carbon-heteroatom bond formation

Doi:10.1016/j.mencom.2013.11.011
(2013)

Article Doi