Journal of the Chemical Society, Dalton Transactions p. 2551 - 2554 (1990)
Update date:2022-08-17
Topics:
Fochi, Giovanni
Runjuan, Xu
Colligiani, Arturo
Reduction of bis(arene)vanadium((0) complexes (1) with potassium in co-ordinating ether solvents gives solutions of the corresponding bis(arene)vanadate(-1) derivatives (2a; arene= benzene) and (2b; arene= mesitylene).Solvated potassium salts were isolated in yields depending on the arene ligands and the type of procedure required.The e.s.r. spectra of the reduction mixtures both in 1,2-dimethoxyethane and hexamethylphosphoramide are discussed.Solutuons of K
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