
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 467 - 472 (1980)
Update date:2022-08-11
Topics:
Wertz, D. W.
Moseley, M. A.
Vibrational assignments of the complexes A reinvestigation of the norbornadiene spectrum was necessary and a new set of assignments is given.The shift in energy of bands I and II and the out-of-plane olefinic C-H wagging modes, as well as the relative energies of the bands associated with the metal-olefin motions are consistent with the total metal-norbornadiene interaction following the order Rh > Pt > Pd and the excent of the ? component being ordered as Rh ca/= Pt > Pd.
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