Journal of Organometallic Chemistry p. 247 - 252 (1987)
Update date:2022-08-11
Topics:
Janecki, Tomasz
Pauson, Peter L.
Pietrzykowski, Antoni
In contrast to o-metallated azobenzene-palladium complexes, 2-(phenylazo)-phenyltricarbonylcobalt is shown to undergo insertion of styrene, methyl acrylate, acrylonitrile and dimethyl fumarate as well as certain alkynes.New tricarbonylcobalt complexes derived from azotoluene, azoanisole and N-t-butylbenzaldimine and a new route to the azobenzene-derived complex are described.
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