
Journal of the Chemical Society. Chemical communications p. 1115 - 1116 (1986)
Update date:2022-08-10
Topics:
Pac, Chyongjin
Miyake, Koji
Matsuo, Toshiro
Yanagida, Shozo
Sakurai, Hiroshi
The photolysis of HFe(CO)4(-) results in the evolution of a 1:1 mixture of H2 and CO under Ar and assists the water gas shift reaction under 1 atm pressure of CO; a suggested mechanism involves the dinuclear reductive elimination of H2 following the photolytic extrusion of CO from HFe(CO)4(-).
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