PHOTOCHEMICAL REARRANGEMENT OF 8-OXABICYCLO(3.2.1.)OCT-6-EN-ONES

DOI: 10.1016/S0040-4039(00)88467-1

Source and publish data:

Tetrahedron Letters p. 6889 - 6892 (1988)

Update date:2022-08-11

Topics:

Authors:

Padwa, Albert

Fryxell, Glen E.

Zhi, Lin

Hornbuckle, Susan F.

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Article abstract of DOI:10.1016/S0040-4039(00)88467-1

Irradiation of 8-oxabicyclo(3.2.1)oct-6-en-2-ones results in a 1,3-acyl rearrangement.The initial photoproduct undergoes a subsequent reaction involving hydrogen transfer followed by intramolecular cycloaddition of a ketene intermediate.

Full text of DOI:10.1016/S0040-4039(00)88467-1

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