Journal of Organic Chemistry p. 1757 - 1759 (1981)
Update date:2022-08-30
Topics:
Stock, Leon M.
Tse, Kwok-Tuen
Vorvick, Linda J.
Walstrum, Steven A.
Relative rate measurements indicate that the palladation reaction, although nonselective, adheres to the selectivity relationship for electrophilic aromatic substitution. Kinetic isotope effects and the dependence of the rate on oxidant concentration implicate arylpalladium(II) and arylpalladium(IV) compounds as intermediates in the reactions leading to biaryls and aryl acetates.
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