Organometallics p. 676 - 678 (1987)
Update date:2022-08-16
Topics:
Ferrara, Joseph D.
Tessier-Youngs, Claire
Youngs, Wiley J.
A copper(I) triflate complex of 1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne (1) has been synthesized and characterized by X-ray crystallography, NMR and IR spectroscopies, and elemental analysis. The copper(I) ion of the complex 3 is chelated by the three alkynes of 1 and semicoordinated by an oxygen of the triflate anion. Complex 3 disproportionates to Cu(0) and Cu(II) in THF solution.
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