Journal of the Chemical Society. Perkin transactions II p. 557 - 560 (1980)
Update date:2022-08-11
Topics:
Audsley, Adrian J.
Quick, Geoffrey R.
Littler, John S.
Evidence is presented, from kinetic and product studies, that the rate-determining step in the oxidation of cyclohexanone by the trisbipyridylruthenium(III) cation is a non-bonded electron-transfer process from the enol form of the substrate.This gives rise to a free radical and a ruthenium(II) species.The subsequent fate of the radical has been investigated.
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