Electron-transfer Oxidation of Organic compounds. Part 5. Oxidation of cyclohexanone by the Tris-2,2'-bipyridylruthenium(III) Cation

DOI: 10.1039/P29800000557

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 557 - 560 (1980)

Update date:2022-08-11

Topics:

Authors:

Audsley, Adrian J.

Quick, Geoffrey R.

Littler, John S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29800000557

Evidence is presented, from kinetic and product studies, that the rate-determining step in the oxidation of cyclohexanone by the trisbipyridylruthenium(III) cation is a non-bonded electron-transfer process from the enol form of the substrate.This gives rise to a free radical and a ruthenium(II) species.The subsequent fate of the radical has been investigated.

Full text of DOI:10.1039/P29800000557

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Adipic acid

Cas No:124-04-9

R&D Labs maybe for 124-04-9

SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 15006126856

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park

Relevant to this article

2-Deoxy-2,3-didehydro-N-acetylneuraminic acid analogs structurally modified by thiocarbamoylalkyl groups at the C-4 position: Synthesis and biological evaluation as inhibitors of human parainfluenza virus type 1

Doi:10.1016/j.bmc.2008.05.055
(2008)
Doi:10.1021/ja01375a047
(1930)
Doi:10.1016/S0040-4039(00)91189-4
(1975)
A facile synthesis of an unsymmetric benzopyranobenzopyran ring system

Doi:10.1016/j.tetlet.2004.06.008
(2004)
Novel catalytic cycle for the synthesis of epoxides from aldehydes and sulfur ylides mediated by catalytic quantities of sulfides and Rh₂(OAc)₄

Doi:10.1021/ja00092a060
(1994)
Experimental and Theoretical Analysis of the Factors determining the Conformation and Stability of Singlet Carbene

Doi:10.1039/c39860000693
(1986)

Article Doi