SYNTHESE A L'AIDE DE SULFONE-XXV. SUBSTITUTION SUR DES SULFONES: L'ANION PHENYLSULFINATE COMME GROUPE PARTANT DANS LA SUBSTITUTION DES SULFONES ALLYLIQUES PAR DES REACTIFS DE GRIGNARD EN PRESENCE DE SELS DE CUIVRE

DOI: 10.1016/S0040-4020(01)91577-7

Source and publish data:

Tetrahedron p. 3283 - 3288 (1983)

Update date:2022-08-11

Topics:

Authors:

Julia, Marc

Righini-Tapie, Anne

Verpeaux, Jean-Noel

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Article abstract of DOI:10.1016/S0040-4020(01)91577-7

Displacement reactions of the sulphinate anion from sulfones by Grignard reagents with copper catalysis take place readily with allylic sulphones.The regio chemistry and stereochemistry of the reaction are discussed.

Full text of DOI:10.1016/S0040-4020(01)91577-7

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