REACTIONS OF ATOMIC MAGNESIUM IN THE BASIC STATE WITH ORGANIC CHLORINE DERIVATIVES AT LOW TEMPERATURES

Article abstract of DOI:10.1016/S0022-328X(00)92559-2

Low-temperature solid-phase reactions of atomic magnesium in the basic state with a number of aliphatic monochlorine derivatives, chlorobenzene, carbon tetrachloride and 1,2-dichloroethane, have been investigated.The nature of the intermediate particles is discussed, the effect of the phase state of a frozen hydrocarbon on its reactivity examined, and the mechanisms of reactions with the participation of radicals and ion radicals proposed.