Journal of the Chemical Society. Chemical communications p. 253 - 254 (1994)
Update date:2022-08-11
Topics:
Bressan, Mario
Forti, Luca
Morvillo, Antonino
In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes α-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min-1 at room temperature.
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