Reinvestigation of the Lewis Acid-mediated Reaction of 3-Aryl-substituted Allyltin Reagents toward Aldehydes. Divergent Stereocontrol of the Product by Lewis Acids

DOI: 10.1246/cl.1994.1429

Source and publish data:

Chemistry Letters p. 1429 - 1432 (1994)

Update date:2022-07-29

Topics: Lewis acid Aldehyde Stereocontrol Reaction Divergent

Authors:

Nishigaichi, Yutaka

Takuwa, Akio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1994.1429

3-Arylallyltin reagents including cinnamyltin stereoselectively gave anti-adducts in the ZnCl2-mediated reaction toward aldehydes in a donating solvent via the 6-membered cyclic transition state.In contrast, the BF3-mediated reaction gave syn-adducts via

Full text of DOI:10.1246/cl.1994.1429

Products guided by the article

Product name:(±)-(2R,3S)-3-phenylpent-4-en-2-ol

Cas No:124844-76-4

R&D Labs maybe for 124844-76-4

Weifang Adde Economic And Trade Co.,LTD.

Contact:86-536-8885548

Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park

Relevant to this article

Hydroxamate anchors for improved photoconversion in dye-sensitized solar cells

Doi:10.1021/ic4010856
(2013)
Mechanistic Studies of Diastereoselective Cyclopropanation via Homochiral Ketals. 1. Dioxolane Structural Effects

Doi:10.1021/jo00294a016
(1990)
Efficient construction of highly substituted and stereodefined cis-fused lactones

Doi:10.1002/ejoc.201000556
(2010)
Tandem suzuki-miyaura cross-coupling/dehydrobromination of 1,1-dibromoalkenes to alkynes with a cyclobutene-1,2-diylbis(imidazolium) salt as catalyst precursor

Doi:10.1055/s-0029-1218848
(2010)
Enantioselective aldol reaction of α-ketoester and Cyclopentaone catalyzed by L-proline

Doi:10.1002/cjoc.201090122
(2010)
Ruthenium-catalyzed regioselective reactions of nitriles and 1,3-dicarbonyl compounds with terminal alkynes ¹

Doi:10.1055/s-0029-1218373
(2009)

Article Doi