Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1031 - 1035 (1992)
Update date:2022-08-18
Topics:
Romakhin, A. S.
Budnikova, Yu. G.
Zaripov, I. M.
Kargin, Yu. M.
Nikitin, E. V.
et al.
An electrochemical method, based on the joint action of nucleophilic and electrophilic reagents on P4, is proposed in order to utilize white phosphorus in the formation of the esters of phosphorus acids.The action of alkoxide ions on white phosphorus in an alcohol medium in the presence of iodine generated at the anode leads to the formation of phosphate esters.A scheme in which the intermediate products are dialkyl and trialkyl phosphites and the side product is dialkyl alkylphosphonate is proposed for the process.Key words: Phosphate esters, white phosphorus, electrosynthesis.
View Moreshijiazhuang shuanglian chemical industry co.,ltd
Contact:0311-82190302
Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway,Shijiazhuang City
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Shanghai Balmxy Pharmaceutical Co., Ltd
Contact:0086-21-24206007
Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Reliable Pharma Technology (Shanghai) Co., Ltd.
Contact:0086-21-67676847-8008
Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Contact:+86-158-05817090
Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Doi:10.1039/c3nj00711a
(2013)Doi:10.1080/07328319808004719
(1998)Doi:10.1002/zaac.201000216
(2010)Doi:10.1021/acs.orglett.0c03241
(2020)Doi:10.1021/jo00893a013
(1975)Doi:10.1271/bbb.110303
(2011)