G. Bhosekar, J. Boeckmann, I. Jeß, C. Näther
ARTICLE
Single-Crystal Structure Analysis
Holstein. We thank Professor Dr. Wolfgang Bensch for access to his
experimental facility.
All investigation was performed with an imaging plate diffraction sys-
α
tem (IPDS-1) with Mo-K -radiation from STOE & CIE. The structure
solution was performed with direct methods using SHELXS-97 [63],
References
2
and structure refinements were performed against F using SHELXL-
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1
2
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C
10
341.71
H
8
N
6
S
2
Zn
C
10
341.71
H
8
N
6
S
2
Zn
C
10 8 6 2
H N S Zn
36, 770.
–
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MW /g·mol
341.71
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crystal system
space group
a /Å
b /Å
c /Å
monoclinic
C2/m
orthorhombic monoclinic
Cmca
9.6383(7)
15.6599(13)
8.4943(8)
90.0
C2/c
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10.2096(10)
10.4294(8)
7.1818(8)
118.94(1)
669.2(1)
293
14.7258(12)
5.5843(3)
17.3102(15)
96.89(1)
1413.2(2)
170
β /°
3
V /Å
1282.1(2)
170
T /K
Z
2
4
4
–
3
D
calc /g·cm
1.696
1.770
1.606
–
1
μ /mm
2.114
2.234
2.027
θ
max / deg
28.00
27.95
27.98
measured refl.
3244
7021
7734
R
int
0.0559
849
0.0741
815
0.0347
1694
unique reflns.
refl.[F > 4σ(F
parameters
[F > 4σ(F
[all data]
o
o
)] 812
772
52
1433
51
88
R
1
wR
o
o
)]
0.0382
0.1039
1.099
0.0293
0.0756
1.027
0.0327
0.0938
1.006
2
GOF
Δρmax/min/e·Å–3
0.65/ –0.68
0.45/–1.27
0.37/–0.50
[
[
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α
radiation (λ = 154.0598 pm)
[
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Acknowledgement
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This project was supported by the Deutsche Forschungsgemeinschaft [47] J. A. Real, G. D. Munno, M. C. Munoz, M. Julve, Inorg. Chem.
(Project No. NA 720/1-1and NA 720/3-1) and the State of Schleswig- 1991, 30, 2701.
2
600
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