Synthesis and chemistry of Cp2Zr(Ph)(THF)+. Selectivity of protolytic and oxidative Zr-R bond-cleavage reactions

DOI: 10.1021/om00051a012

Source and publish data:

Organometallics p. 1268 - 1274 (1991)

Update date:2022-08-11

Topics:

Authors:

Borkowsky, Samuel L.

Jordan, Richard F.

Hinch, Garry D.

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Article abstract of DOI:10.1021/om00051a012

The neutral complexes Cp₂Zr(R)₂ (R = CH₃ (1), CH₂Ph (2)) react with [Cp′₂Fe][BPh₄] in THF via oxidative Zr-R bond cleavage to yield [Cp₂Zr(R)(THF)][BPh₄] (R = CH₃

Full text of DOI:10.1021/om00051a012

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