Synthesis and chemistry of Cp2Zr(Ph)(THF)+. Selectivity of protolytic and oxidative Zr-R bond-cleavage reactions

DOI: 10.1021/om00051a012

Source and publish data:

Organometallics p. 1268 - 1274 (1991)

Update date:2022-08-11

Topics:

Authors:

Borkowsky, Samuel L.

Jordan, Richard F.

Hinch, Garry D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00051a012

The neutral complexes Cp₂Zr(R)₂ (R = CH₃ (1), CH₂Ph (2)) react with [Cp′₂Fe][BPh₄] in THF via oxidative Zr-R bond cleavage to yield [Cp₂Zr(R)(THF)][BPh₄] (R = CH₃

Full text of DOI:10.1021/om00051a012

Products guided by the article

Product name:Bis(cyclopentadienyl)dimethylzirconium

Cas No:12636-72-5

R&D Labs maybe for 12636-72-5

Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
Jurong Huaheng Natural Biological Products Factory

website:http://www.risebiochem.com

Contact:+86-13921007726

Address:Chuncheng town,Jurong city,Jiangsu province,China
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:No.199, Ningbo Avenue, Fengxin industrial park, Fengxin county, Yichun city, Jiangxi
Shanghai Dianyang Industry Co.,ltd

Contact:+86 21 6492 4669

Address:Chejing RD, Songjiang District, Shanghai, China

Relevant to this article

Generation of interhalogen fluorides under mild conditions: A comparison of sluggish and reactive interhalogen fluorides

Doi:10.1021/jo972319g
(1999)
Mechanism of forming trimer, self-assembling nano-particle and inhibiting tumor growth of small molecule CIPPCT

Doi:10.1039/c4md00158c
(2014)
The rhodium complex of bis(diphenylphosphinomethyl)dopamine-coated magnetic nanoparticles as an efficient and reusable catalyst for hydroformylation of olefins

Doi:10.1039/c5nj01170a
(2015)
Comparative metabolism of N-tert-butyl-N-[1-(1-oxy-pyridin-4-yl)-ethyl]- and N-tert-butyl-N-(1-phenyl-ethyl)-nitroxide by the cytochrome P450 monooxygenase system

Doi:10.1021/tx025510g
(2002)
Synthesis and crystal structure of (Xe₂F₁₁⁺)₂NiF₆ ^2-

Doi:10.1021/ic00314a008
(1989)
Two New Sesquiterpenoid Ketones from Cassia Oil

Doi:10.1002/hlca.19800630631
(1980)

Article Doi