Angewandte Chemie - International Edition p. 9825 - 9828 (2012)
Update date:2022-08-16
Topics:
Yang, Yang
Fu, Xingnian
Chen, Jianwei
Zhai, Hongbin
As easy as ABCD: (-)-Jiadifenin was synthesized in eighteen reaction steps from 1-[(E)-(4′-bromo-2′-butenyl)oxy]-4-methoxybenzene. Key features of this synthesis include: 1) Ireland-Claisen rearrangement to produce the two contiguous quaternary centers at
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Doi:10.1021/jo01258a047
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