
Journal of the Chemical Society. Chemical communications p. 1017 - 1018 (1986)
Update date:2022-08-30
Topics:
Lathbury, David
Gallagher, Timothy
The 3,5-disubstituted pyrrolizidine alkaloid (8) has been synthesised using, as a key step, the cyclisation of the allenic oxime E-(3) to generate a 5-substituted nitrone (4); under the same cyclisation conditions Z-(3) reacts via oxygen to give (9).
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