Oxazoles from β-acyloxy-N,N-bis(trimethylsilyl)enamines

DOI: 10.1016/S0040-4039(00)88885-1

Source and publish data:

Tetrahedron Letters p. 1945 - 1948 (1990)

Update date:2022-08-02

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Authors:

Cunico Cunico

Kuan Kuan

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Article abstract of DOI:10.1016/S0040-4039(00)88885-1

Sequential addition of methyllithium and acyl chlorides to O-trimethylsilyl acetyltrimethylsilane cyanohydrin affords β-acyloxy-N,N-bis(trimethylsilyl)enamines which cyclize to 2-substituted-4,5-dimethyloxazoles under thermolysis or trimethylsilyl trifluoromethanesulfonate treatment.

Full text of DOI:10.1016/S0040-4039(00)88885-1

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