A NEW DOUBLE BOND BRIDGED DIBENZODITHIOCIN: PREPARATION, CHARACTERIZATION, AND ITS TRANSANNULAR P?-(>S+-S+<) INTERACTION

DOI: 10.1016/S0040-4039(00)99130-5

Source and publish data:

Tetrahedron Letters p. 2805 - 2808 (1989)

Update date:2022-08-29

Topics:

Authors:

Fujihara, Hisashi

Chiu, Jer-Jye

Furukawa, Naomichi

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Article abstract of DOI:10.1016/S0040-4039(00)99130-5

A new heterocyclic compound, 1,11-(etheno)-5H,7H-dibenzo<1,5>dithiocin (1) has been prepared by treatment of mono-sulfonium salt of 1,11-(methanothiomethano)-5H,7H-dibenzo<1,5>dithiocin with t-BuOK in a one step; the reactivities and the transannular p?-(>S⁺-S⁺<) interaction in 1 are described.

Full text of DOI:10.1016/S0040-4039(00)99130-5

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