Journal of Organic Chemistry p. 3742 - 3752 (1984)
Update date:2022-08-24
Topics:
Kokke, W. C. M. C.
Shoolery, James N.
Fenical, William
Djerassi, Carl
A photosynthetic marine Chrysophyte (unicellular alga) was cultured in a medium containing labeled methionine (methyl-13C, methyl-d3).The 2H and 13C distribution in the alkyl substituents of the sterols was determined by 2H and 13C NMR.Although two novel cyclopropyl sterols - (24R,28R)-
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