Chemistry Letters p. 1011 - 1012 (1995)
Update date:2022-08-10
Topics:
Sasaki, Shigeru
Iyoda, Masahiko
A series of di-, tri-, tetra-, and pentaamines were synthesized as precursors for corresponding di-, tri-, tetra-, and penta(aminium radical-cations) by the aryl-N bond formation reaction between aryl iodides and in situ prepared copper amide in refluxing pyridine.Cyclic voltammograms of meta-connected derivatives consisted of irreversible waves which imply side reactions in addition to oxidation to aminium radical-cations.
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