Chemistry of Natural Compounds p. 494 - 496 (1991)
Update date:2022-08-24
Topics:
Odinokov, V. N.
Kukovinets, O. S.
Sakharova, N. I.
Tolstikov, G. A.
The synthesis has been effected of octa-2E,6E-diene-1,8-diol diisovalerate - the sex pheromone of the Crimean click beetle Agriotes tauricus - by the carboxymethylenation of the readilly available 6-methylhept-5-en-2-one, the allyl oxidation of a terminal methyl group, reduction of the ester fraction, and interaction of the diol so obtained with isovaleryl chloride.The required pheromone can also bee obtained from available cyclic oligomers of isoprene.
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