Journal of the American Chemical Society p. 3904 - 3909 (1991)
Update date:2022-08-05
Topics:
Rathjen
Margaretha, Paul
Wolff, Steven
Agosta, William C.
Photochemical cycloaddition of 3-alkynylcycloalkenones 3a,b,c and 4 with tetramethylethylene (8) at ～40°C leads to mixtures of 1:1 adducts that arise largely from 1,5 closure of the biradical intermediate (eq 1), providing examples of a novel [3 + 2] cycl
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