STEREOSELECTIVE SYNTHESIS OF 1,2-TRANS-1-THIOGLYCOSES USING ALUMINIUM CHLORIDE: EVIDENCE FOR 1,2-CIS-1-CHLOROGLYCOPYRANOSYLPERACETATES AS THE ACTUAL REACTION INTERMEDIATES

DOI: 10.1016/S0040-4039(00)96105-7

Source and publish data:

Tetrahedron Letters p. 2295 - 2296 (1987)

Update date:2022-08-10

Topics:

Authors:

Rajanikanth, B.

Seshadri, R.

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Article abstract of DOI:10.1016/S0040-4039(00)96105-7

Synthesis of 1,2-trans-1-thioglycosylacetates has been achieved in excellent yields from corresponding 1,2-trans-glycosylacetates using aluminium chloride via 1,2-cis-1-chloroglycopyranosylacetates with retention of configuration.

Full text of DOI:10.1016/S0040-4039(00)96105-7

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