Tetrahedron p. 15701 - 15710 (1997)
Update date:2022-09-26
Topics:
Matsuya, Yuji
Itoh, Takashi
Nagata, Kazuhiro
Ohsawa, Akio
A new dehydrazination reaction of arylhydrazines using nitric oxide and oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selectivity as a counterpart of the azide synthesis by the conventional methods. The generally and reaction mechanism were also investigated.
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