Extraordinary Diastereoselectivity Coupled to Altered Structure of Dipeptide Esters

DOI: 10.1246/cl.1993.1303

Source and publish data:

Chemistry Letters p. 1303 - 1304 (1993)

Update date:2022-08-28

Topics:

Authors:

Matsumoto, Yoko

Matsumoto, Yoshito

Inoue, Junichi

Ueoka, Ryuichi

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Article abstract of DOI:10.1246/cl.1993.1303

The diastereoselectivity for the hydrolysis of Z-D(L)-Phe-L-Phe p-methoxycarbonylphenyl ester was maximized (k_s^DL/k_s^LL=34) at the optimum temperature (30 deg C).This could be attributed to the conformational change in the DL isomer, which was supported by the circular dichroism measurements.

Full text of DOI:10.1246/cl.1993.1303

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