Journal of Organometallic Chemistry p. 123 - 130 (1981)
Update date:2022-08-16
Topics:
Lehmkuhl, Herbert
Doering, Ingo
Nehl, Hans
The dialk-2-enylzinc compounds I-IV add to ethylene, oct-1-ene and 3,3-dimethylcyclopropene to give the corresponding di-alk-4-enylzinc compounds VI-IX (88-98percent yield), XV and XVI (90-94percent yield), XVII (7percent) and XXIIIa-XXVIa (91-98percent yield).Additions to XIII are regioselective with Zn -> C(1) while stereoselective cis-addition to XXII is observed.
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