Journal of Organic Chemistry p. 823 - 824 (1993)
Update date:2022-08-30
Topics:
Beak, Peter
Yum, Eul Kgun
A α-metalo amine synthetic equivalent of an unactivated primary amine, 1-lithio-3-hydroxy-1-propylamine (7) is provided by the lithiation of N-Boc-2-methyltetrahydro-1,3-oxazine (8) to give 9 which on reaction with electrophiles and hydrolysis gives derivatives of 1-substituted 3-hydroxy-1-propylamines 10-24.
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