HYDRIDE REDUCTION OF THE CATION 5-C5H5)Fe(Ph2CH2CH2PPh2)CO>PF6; FORMATION OF (η5-C5H5)FeH(CO)(Ph2CH2CH2PPh2) AND ELIMINATION OF H2 FROM 5-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2)

DOI: 10.1016/S0022-328X(00)84809-3

Source and publish data:

Journal of Organometallic Chemistry p. C7 - C8 (1982)

Update date:2022-08-10

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Authors:

Davies, Stephen G.

Hibberd, John

Simpson, Stephen J.

Watts, Oliver

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Article abstract of DOI:10.1016/S0022-328X(00)84809-3

(η⁵-C5H5)FeH(CO)(Ph2PCH2CH2PPh2), formed in the LiAlH4 reduction of the cation of <(η⁵C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6, can be converted into <(η⁵-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2), which undergoes thermal and photochemical elim

Full text of DOI:10.1016/S0022-328X(00)84809-3

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