REDUCTIVE TRANSFORMATIONS - 14. REGIOSELECTIVE ADDITION OF CARBANIONS TO THE "AROMATIC" PYRENE ISOMER DICYCLOPENTA(ef,kl)HEPTALENE

DOI: 10.1016/S0040-4039(00)74871-4

Source and publish data:

Tetrahedron Letters p. 735 - 738 (1991)

Update date:2022-08-16

Topics:

Authors:

Alexander, Juergen

Baumgarten, Martin

Klabunde, Kay-Uwe

Muellen, Klaus

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Article abstract of DOI:10.1016/S0040-4039(00)74871-4

We report on a LUMO-controlled nucleophilic addition to the pyrene isomer 1.Treatment of 1 with organometallic reagents and subsequent quenching of the resulting monoanionic intermediates yield bridged <14>annulenes.

Full text of DOI:10.1016/S0040-4039(00)74871-4

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