Journal of Physical Chemistry p. 9738 - 9741 (1992)
Update date:2022-08-18
Topics:
Biggs, Karen R.
Gomme, Robin A.
Graham, John T.
Ogden, J. Steven
Samples of the solids MIO3 (M = Li, Na, K, Rb, Cs) have been vaporized in vacuo and the ternary products characterized by mass spectrometry, and by infrared spectroscopy in low-temperature nitrogen, oxygen and argon matrices.The molecular species KiO3, RbIO3, and CsIO3 have been identified for the first time and their IR spectra shown to be consistent with overall C3v symmetry involving tridentate coordination.This conclusion is further confirmed, in the case of CsIO3 isolated in argon, by a detailed analysis of (18)O isotope patterns.In contrast, samples of LiIO3 and NaIO3 appeared to undergo decomposition to the iodide and oxygen.
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