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Synthesis and reactivity of bis(alkyloxalyl) and alkoxycarbonyl alkyloxalyl iron complexes and (R, R'=Me or Et): evidence for reductive elimination of oxalate

DOI: 10.1016/0022-328X(94)88044-1

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Journal of Organometallic Chemistry p. 175 - 184 (1994)

Update date:2022-08-11

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Authors:

Laurent, PascaleLaurent, Pascale

Salauen, Jean-YvesSalauen, Jean-Yves

Gall, Gwenaeelle LeGall, Gwenaeelle Le

Sellin, MurielleSellin, Murielle

Abbayes, Herve desAbbayes, Herve des

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Article abstract of DOI:10.1016/0022-328X(94)88044-1

The new complexes cis- (R=Me or Et) and cis- (R,R'=Me, Et or i-Pr) have been synthesized.The bis-(alkyloxalyl) complexes decarbonylate at +12 deg C to their alkoxycarbonyl alkyloxalyl homologues.The latter decompo

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Full text of DOI:10.1016/0022-328X(94)88044-1

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