Tetrahedron Asymmetry p. 2177 - 2180 (1996)
Update date:2022-08-17
Topics:
Martinez, A. Garcia
Teso Vilar
Garcia Fraile
De La Moya Cerero
Martinez Ruiz
Subramanian
The cleavage of the C1-C2 bond in norbornate derivatives is accomplished by base-promoted hydrolysis of α-nitroketones, periodate oxidation or Beckmann fragmentation of suitable precursors prepared from the 2-norbornanones 1. These reactions are the basis for the synthesis of the 3-substituted homochiral cyclopentanones 6, 10 or 15.
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