Chemistry Letters p. 1471 - 1474 (1983)
Update date:2022-08-16
Topics:
Kagiya, Tsutomu
Kimura, Ryoji
Komuro, Chikara
Sakano, Koichi
Nishimoto, Sei-ichi
Remarkable promotion of the hydroxylation of thymine to give thymine glycol with almost complete depression of side reactions by 2,2,6,6-tetramethylpiperidine-1-oxyl (TMPO.) derivatives was observed in the γ-radiolyses of the N2- and N2O-saturated aqueous solutions.In the O2-saturated solution, TMPO. depressed the thymine conversion close to the level under N2 while promoted the formation of thymine glycol to some extent by decreasing side reactions.
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