Radical cycloaddition by nickel(II) complex-catalyzed electroreduction. A method for preparation of pyrrolopyridine and pyrrolopyrrole derivatives

DOI: 10.1248/cpb.44.2020

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Chemical and Pharmaceutical Bulletin p. 2020 - 2024 (1996)

Update date:2022-08-29

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Authors:

Ozaki, Shigeko

Mitoh, Shizue

Ohmori, Hidenobu

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Article abstract of DOI:10.1248/cpb.44.2020

Cycloalkano[a]pyrroles were obtained by reductive radical cycloaddition of 1-(2-iodoethyl)pyrrole and activated olefins or by cyclization of 1-(ω- iodoalkyl)pyrroles, through electroreduction of the iodides using nickel(II) complex as an electron-transfer catalyst.

Full text of DOI:10.1248/cpb.44.2020

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