Enantioselective approaches to rhodium catalysed aldol-type reactions

DOI: 10.1080/00397919308011211

Source and publish data:

Synthetic Communications p. 1251 - 1259 (1993)

Update date:2022-08-28

Topics:

Authors:

Roos Roos

Haines Haines

Raab Raab

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Article abstract of DOI:10.1080/00397919308011211

Homochiral catalysts, [Rh(norbornadiene)-(homochiral diphosphine)]⁺ X^-/H₂, were tested to assess possible enantiocontrol in the aldol-type coupling of activated vinyl components with aldehydes. A related approach, via in situ rhodium silyl enolates, was also investigated.

Full text of DOI:10.1080/00397919308011211

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