The thermal conversion of 6,6-difluorobicyclo[3.1.0]hex-2-ene to fluorobenzene. A novel mechanism

DOI: 10.1016/0040-4039(91)80593-U

Source and publish data:

Tetrahedron Letters p. 3933 - 3936 (1991)

Update date:2022-08-03

Topics:

Authors:

Dolbier Jr.

Keaffaber

Burkholder

Sellers Sellers

Koroniak

Pradhan Pradhan

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Article abstract of DOI:10.1016/0040-4039(91)80593-U

The dehydrofluorinative aromatization reaction of 6,6-difluorobicyclo[3.1.0]hex-2-ene (1) has been found to proceed via a two-step mechanism, the first being a novel, rate-determining homolytic H-shift process.

Full text of DOI:10.1016/0040-4039(91)80593-U

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