Journal of the Chemical Society. Perkin transactions II p. 557 - 558 (1985)
Update date:2022-08-16
Topics:
Jones, John R.
Pearson, Gerd M.
Spinelli, Domenico
Consiglio, Giovanni
Arnone, Caterina
A series of 4- and 5-substituted 2-(<3H>acetyl)thiophenes have been prepared and the kinetics of the hydroxide-catalysed detritiation studied at 25.0 deg C.The second-order detritiation rate constants parallel those observed for the corresponding meta- and para-substituted acetophenones but as the reaction constant ρ is higher (1.61) the range of reactivity is much wider than that witnessed for the acetophenones.
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