Tungsten complex induced dehydration of 2,3-dihydroxycarboxylic acids to α-keto acids

DOI: 10.1016/S0040-4039(00)61777-X

Source and publish data:

Tetrahedron Letters p. 6791 - 6794 (1992)

Update date:2022-08-16

Topics:

Authors:

Schwartz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61777-X

In the absence of added base, WOCl₄ induces rapid dehydration of the title compounds to give α-keto acids. A mechanism is suggested based on a neighboring group effect.

Full text of DOI:10.1016/S0040-4039(00)61777-X

Products guided by the article

Product name:Ethyl 3-oxobutanoate sodium salt

Cas No:15933-07-0

R&D Labs maybe for 15933-07-0

Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Shanghai Norky Pharmaceutical Co., LTD.

website:http://www.norkypharm.com

Contact:86-21-61075300

Address:1165 Jiangning Road, Office 1502, Shanghai, China
Wuhan Konberd Biotech Co., Ltd.

Contact:+86-27-87205925

Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Henan zhongda Biological Engineering Co., Ltd

Contact:86-28-18109029985

Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
Quzhou Hopemax Chemical Technology Co.Ltd

Contact:86-570-3036007

Address:Room 801,Building 2,Wealth Center,No.51,Xujiang Road,Quzhou,China.

Relevant to this article

Potent anti-platelet constituents from centaurea iberica

Doi:10.3390/molecules16032053
(2011)
Doi:10.1016/S0040-4039(01)86752-6
(1979)
Doi:10.1021/jo00881a022
(1976)
Diaminopyrimidines, diaminopyridines and diaminopyridazines as histamine H₄ receptor modulators

Doi:10.1016/j.bmcl.2014.12.027
(2015)
Reduction and reconstruction of Co₃O₄ nanocubes upon carbon deposition

Doi:10.1021/jp052551n
(2005)
Synthesis and antibacterial activity of 3-benzylamide derivatives as FtsZ inhibitors

Doi:10.1016/j.bmcl.2017.02.032
(2017)

Article Doi