
Journal of Chemical Physics p. 3874 - 3881 (1981)
Update date:2022-08-11
Topics:
Messing, I.
Filseth, S. V.
Sadowski, C. M.
Carrington, Tucker
CH(X 2Π) was produced by multiple infrared photon dissociation of CH3OH in the presence of excess atomic oxygen or nitrogen.Time-resolved measurements of relative CH concentrations were made at 298 K with a tunable dye laser.Rate constants deduced from the dependence of CH decay rate on atom concentration are (9.5 +/- 1.4) * 10-11 cm3 s-1 for CH + O and (2.1 +/- .5) * 10-11 cm3 s-1 for CH + N.
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