Reductive trans-2,6-diallylation of pyridines with allylboranes. Synthesis of trans- and cis-2,6-diallyl-1,2,5,6-tetrahydropyridines and their deuterated derivatives

DOI: 10.1007/BF00699842

Source and publish data:

Russian Chemical Bulletin p. 645 - 656 (1994)

Update date:2022-08-29

Topics:

Authors:

Bubnov, Yu. N.

Shagova, E. A.

Evchenko, S. V.

Ignatenko, A. V.

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Article abstract of DOI:10.1007/BF00699842

The reductive trans-2,6-diallylation of pyridines with trialllyl and allyl(dialkyl)boranes has been discovered.Heating (40-100 deg C) of pyridine, deuteropyridine, or 3-bromopyridine complexes with triallylborane in the presence of alcohols (ROH or CH3OD)

Full text of DOI:10.1007/BF00699842

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