Reductive trans-2,6-diallylation of pyridines with allylboranes. Synthesis of trans- and cis-2,6-diallyl-1,2,5,6-tetrahydropyridines and their deuterated derivatives

DOI: 10.1007/BF00699842

Source and publish data:

Russian Chemical Bulletin p. 645 - 656 (1994)

Update date:2022-08-29

Topics:

Authors:

Bubnov, Yu. N.

Shagova, E. A.

Evchenko, S. V.

Ignatenko, A. V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00699842

The reductive trans-2,6-diallylation of pyridines with trialllyl and allyl(dialkyl)boranes has been discovered.Heating (40-100 deg C) of pyridine, deuteropyridine, or 3-bromopyridine complexes with triallylborane in the presence of alcohols (ROH or CH3OD)

Full text of DOI:10.1007/BF00699842

Products guided by the article

Product name:(2R,6R)-2,6-DIALLYL-1,2,3,6-TETRAHYDROPYRIDINE

Cas No:138617-50-2

R&D Labs maybe for 138617-50-2

Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
xujianqiang

Contact:86-21-57725962

Address:shanghai
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:13th Floor, Xinbao Technology Industrial Park, No. 2 Ruixiang Road, Huangpu District, Guangzhou,Guangdong,China
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China

Relevant to this article

Catalyst/cocatalyst nuclearity effects in single-site polymerization. Enhanced polyethylene branching and α-olefin comonomer enchainment in polymerizations mediated by binuclear catalysts and cocatalysts via a new enchainment pathway

Doi:10.1021/ja0201698
(2002)
{Mo₇₂Cr₃₀} nanocluster as a novel self-separating catalyst for hydrogen peroxide olefin epoxidation

Doi:10.1016/j.catcom.2017.03.006
(2017)
Regioselective allylic alkylation and etherification catalyzed by in situ generated N-heterocyclic carbene ruthenium complexes

Doi:10.1016/j.tetlet.2005.11.051
(2006)
Carving Out Pores in Redox-Active One-Dimensional Coordination Polymers

Doi:10.1002/anie.201807506
(2018)
Synthesis and cytotoxic activities of organometallic Ru(II) diamine complexes

Doi:10.1016/j.bioorg.2020.103793
(2020)
Doi:10.1039/c19670000174
(1967)

Article Doi