STEREOSPECIFIC CONSTRUCTION OF EXO-TETRASUBSTITUTED OLEFINS. THE EFFICIENT SYNTHESIS OF CYANO-CARBACYCLINS

DOI: 10.1016/S0040-4039(00)98672-6

Source and publish data:

Tetrahedron Letters p. 3491 - 3494 (1985)

Update date:2022-08-25

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Authors:

Shibasaki, Masakatsu

Sodeoka, Mikiko

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Article abstract of DOI:10.1016/S0040-4039(00)98672-6

Cyano-carbacyclins (2 and 3) were efficiently sythesized using the stereospecific 1,4-hydrogenation of the corresponding conjugated diene 10a catalyzed by the arene.Cr(CO)3 complex as a key step.

Full text of DOI:10.1016/S0040-4039(00)98672-6

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