Generation and trapping of ortho-substituted thionitrosobenzenes: Competitive Diels-Alder and ene reactions with dimethylbutadiene

DOI: 10.1016/0040-4039(91)80134-R

Source and publish data:

Tetrahedron Letters p. 7459 - 7462 (1991)

Update date:2022-08-16

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Authors:

Bryce Bryce

Heaton Heaton

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Article abstract of DOI:10.1016/0040-4039(91)80134-R

Transient thionitrosoarenes, ArN=S, (2) that bear a substituent (CN, Br or Me) ortho to the reactive N=S group have been generated by two entirely different routes and intercepted with dimethylbutadiene to afford mixtures of Diels-Alder and ene adducts, (

Full text of DOI:10.1016/0040-4039(91)80134-R

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