UNUSUAL REARRANGEMENT OF ?-VINYLPALLADIUM COMPLEXES INTO η2-OLEFIN COMPLEXES. THE STRUCTURE OF (η2-1-TRIPHENYLPHOSPHONIUM-2-CARBOMETHOXYETHYLENE)-(TRIPHENYLPHOSPHINE)IODOPALLADATE

DOI: 10.1016/0022-328X(85)80110-8

Source and publish data:

Journal of Organometallic Chemistry p. 119 - 130 (1985)

Update date:2022-08-23

Topics:

Authors:

Rybin, L. V.

Petrovskaya, E. A.

Rubinskaya, M. I.

Kuz'mina, L. G.

Struchkov, Yu.T.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(85)80110-8

β-Substituted ?-vinylpalladium complexes (I) (X = Cl, I; R = Me, Et) have been obtained by interaction of the E- and Z-β-halogen acrylates with tetrakis(triphenylphosphine)palladium.On heating complexes I rearrange into isomeric η²-olefin-ylidepalladium complexes (II).The structure of these complexes has been established by X-ray study of the compound with X = I, R = Me.

Full text of DOI:10.1016/0022-328X(85)80110-8

Products guided by the article

Product name:Bis(triphenylphosphine)palladium(II) chloride

Cas No:13965-03-2

R&D Labs maybe for 13965-03-2

ANGCHEN BRIGHTCHEM CO., LTD

website:http://www.angchenchem.com

Contact:+86-510-88302099 82327577

Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Shanghai PotentPharm Science and Technology Co.,Ltd

Contact:86-021-51969655

Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China

Relevant to this article

PHOTOCATALYSIS ON Ti-Al BINARY METAL OXIDES: ENHANCEMENT OF THE PHOTOCATALYTIC ACTIVITY OF TiO₂ SPECIES.

Doi:10.1021/j100313a039
(1988)
Doi:10.1016/0031-9422(82)80061-7
(1982)
Tuning the photo-physical properties of BODIPY dyes: Effects of 1, 3, 5, 7- substitution on their optical and electrochemical behaviours

Doi:10.1016/j.dyepig.2019.04.054
(2019)
Synthesis of bredinin from 5-aminoimidazole-4-carboxamide-ribofuranoside (AICA riboside)

Doi:10.1248/cpb.32.1644
(1984)
Doi:10.1021/ja01155a558
(1951)
A one-step synthesis of 2-(2-pyridyl)-3H-indol-3-one N-oxide: Is it an efficient spin trap for hydroxyl radical?

Doi:10.1021/jo0006122
(2000)

Article Doi