UNUSUAL REARRANGEMENT OF ?-VINYLPALLADIUM COMPLEXES INTO η2-OLEFIN COMPLEXES. THE STRUCTURE OF (η2-1-TRIPHENYLPHOSPHONIUM-2-CARBOMETHOXYETHYLENE)-(TRIPHENYLPHOSPHINE)IODOPALLADATE

DOI: 10.1016/0022-328X(85)80110-8

Source and publish data:

Journal of Organometallic Chemistry p. 119 - 130 (1985)

Update date:2022-08-23

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Authors:

Rybin, L. V.

Petrovskaya, E. A.

Rubinskaya, M. I.

Kuz'mina, L. G.

Struchkov, Yu.T.

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(85)80110-8

β-Substituted ?-vinylpalladium complexes (I) (X = Cl, I; R = Me, Et) have been obtained by interaction of the E- and Z-β-halogen acrylates with tetrakis(triphenylphosphine)palladium.On heating complexes I rearrange into isomeric η²-olefin-ylidepalladium complexes (II).The structure of these complexes has been established by X-ray study of the compound with X = I, R = Me.

Full text of DOI:10.1016/0022-328X(85)80110-8

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