Journal of the American Chemical Society p. 1126 - 1129 (1983)
Update date:2022-08-17
Topics:
Farneth, William D.
Zimmerman, Patrick G.
Hogenkamp, Derk J.
Kennedy, Scott D.
The heterogeneous decomposition of 2-propanol vapor in the presence of CuO solid has been induced by infrared laser radiation.The reaction produces both acetone by dehydrogenation and propene by dehydration.Yields and branching ratios are quite sensitive to experimental variables.Experiments have been carried out in one of two basic configurations: either the CuO surface is parallel to laser beam as it passed through the cell or the CuO surface is perpendicular to and intercepts the laser beam.Reaction occurs in both geometries although much more readily in the latter.Branching ratios from 0.02 to 6.0 have been observed.
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