Acidity comparison between ion-exchanged clay montmorillonites by using silylation of alcohol

DOI: 10.1016/S0040-4039(00)77519-8

Source and publish data:

Tetrahedron Letters p. 1171 - 1172 (1993)

Update date:2022-08-30

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Authors:

Onaka, Makoto

Hosokawa, Yasutaka

Higuchi, Katsumi

Izumi, Yusuke

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Article abstract of DOI:10.1016/S0040-4039(00)77519-8

Acidities of various ion-exchanged clay montmorillonites in organic media are compared by use of the reaction of a primary alcohol with allyltrimethylsilane. The order of catalytic activities of the montmorillonites coincide with a sequence of hydration enthalpy of exchanged cations in the clays.

Full text of DOI:10.1016/S0040-4039(00)77519-8

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