Journal of the Chemical Society. Chemical communications p. 1381 - 1382 (1994)
Update date:2022-08-25
Topics:
Hiscock, Steven D.
Isaacs, Neil S.
King, Malcolm D.
Young, David J.
The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
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